{2}-Metallocryptands of Iron and Gallium: Synthesis, Structure, and Properties [1]
نویسندگان
چکیده
Rolf W. Saalfrank, Uwe Reimann, Andreas Scheurer, Frank Hampel, Cornelia Goebel, and Regine Herbst-Irmer a Department Chemie und Pharmazie, Lehrstuhl für Anorganische und Allgemeine Chemie, Universität Erlangen-Nürnberg, Egerlandstraße 1, 91058 Erlangen, Germany b Department Chemie und Pharmazie, Organische Chemie, Universität Erlangen-Nürnberg, Henkestraße 42, 91054 Erlangen, Germany c Institut für Anorganische Chemie, Universität Göttingen, Tammannstraße 4, 37077 Göttingen, Germany
منابع مشابه
Synthesis and Crystal Structure of a Novel Six-Coordinate Gallium (III) Complex
The reaction of gallium (III) nitrate octahydrate with the proton transfer compound (pydaH2)2+ (pydc)2– ( where pyda is 2,6-pyridinediamine and pydcH2 is 2,6-pyridinedicarboxylic acid) leads to the formation of (C5H8N3) [Ga(C7H3NO4)2] · 4H2O · CH3OH. The crystal system of the anionic complex is triclinic with space group Pī and two molecules per unit cell. The unit cell parameters are a=10.23...
متن کاملSynthesis of Iron Oxide Nanoparticles using Borohydride Reduction
Iron oxide (Fe2O3) nanoparticles were synthesized by a simple approach using sodium borohydride (NaBH4) and Iron chloride hexahydrate (FeCl3.6H2O). Their physicochemical properties were characterized by high resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and electron dispersive spectroscopy (EDS). XRD pattern showed that the iron...
متن کاملSynthesis of Iron Oxide Nanoparticles using Borohydride Reduction
Iron oxide (Fe2O3) nanoparticles were synthesized by a simple approach using sodium borohydride (NaBH4) and Iron chloride hexahydrate (FeCl3.6H2O). Their physicochemical properties were characterized by high resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM), X-ray diffraction (XRD) and electron dispersive spectroscopy (EDS). XRD pattern showed that the iron...
متن کاملNew Method of Synthesis of Stable Zero Valent Iron Nanoparticles (Nzvi) by Chelating Agent Diethylene Triamine Penta Acetic Acid (DTPA) and Removal of Radioactive Uranium From Ground Water by using Iron Nanoparticle
Nowdays, iron nanoparticles due to their unique characteristics are used in all of sciences and technology. These nano particles due to their electrical, magnetic, optical and catalytic properties and having high area and activity that is promped by their small size and most importantly many scientists from the entire world are interested in th...
متن کاملImprove Synthesis of Iron Oxide Nanorode with Hydrothermal Method
Maghemite and magnetite nanoparticles and nanorode are now losing interests in the field of nanobiotechnology and pharmaceutical for their applications. This paper reports on a hydrothermal process for the synthesis of Fe2 O3 in the γ-phases nanorodes, when the hydrothermal temperature was 100 ̊ C. The uniqueness of the method lies in the use of ferrous ammonium sulphate, hexamine was added as t...
متن کامل